| Value XD Ltd | Information & communication | 2016 |
| VB Charitable Trust | Professional & scientific | 2013 |
| VDA Global Ltd | Information & communication | 2024 |
| Vehicle Express Logistics Ltd | Transport & logistics | 2021 |
| Vemia Ltd | Wholesale & retail | 2023 |
| Vertex Solutions Limited | Construction | 2018 |
| Vertical Frontiers Limited | Arts & recreation | 2014 |
| Viator Electrical Contractors Limited | Construction | 2011 |
| Videostream Emea Ltd | Professional & scientific | 2015 |
| Virtec Roofing Ltd | Construction | 2026 |
| Vit-D Tanning Devon Limited | Other services | 2016 |
| Voaden and SON Surfacing Ltd | Construction | 2025 |
| Volius Limited | Manufacturing | 2018 |
| VS Bar Ltd | Hospitality | 2025 |
| W H Toms Building Services Ltd | Construction | 2022 |
| W T Butt Limited | Construction | 2011 |
| WAG Your Tail Ltd | Manufacturing | 2024 |
| Waie Inn Limited | Hospitality | 2002 |
| Wakeman Property Limited | Real estate | 2013 |
| Warmer Services Limited | Construction | 2015 |
| Warren Mount Properties Limited | Professional & scientific | 2015 |
| Wattshnoo Ltd | Information & communication | 2014 |
| Waverley Digital Marketing Ltd | Information & communication | 2018 |
| WD Property Holdings Ltd | Real estate | 2020 |
| Wedge Sales Consultancy Ltd | Professional & scientific | 2023 |
| Wedgeheath Limited | Extraterritorial | 2022 |
| Wellnest Retail Ltd | Wholesale & retail | 2026 |
| Wells Court Developments Ltd | Construction | 2020 |
| Wells Court Limited | Health & social care | 2001 |
| Wellspring Connect | Other services | 2025 |
| WEP Fire Protection Limited | Manufacturing | 2018 |
| West Aish Farm Limited | Real estate | 2022 |
| West Country Confectionery Ltd | Wholesale & retail | 2013 |
| West Heath Enterprises Limited | Wholesale & retail | 2025 |
| Westbourne Trading Company Ltd | Wholesale & retail | 2020 |
| Westcountry Groundworks (SW) Limited | Construction | 2014 |
| Westcountry Groundworks Limited | Construction | 2003 |
| Westcountry Pond Services Ltd | Construction | 2017 |
| Western Venture Group Limited | Administrative & support | 1996 |
| Westward Barbell Ltd | Arts & recreation | 2016 |
| Westwave Carpentry Ltd | Real estate | 2025 |
| Westwood Farm Limited | Agriculture & fishing | 2003 |
| WET Web Ltd | Information & communication | 2021 |
| Whisky Rose Developments Limited | Real estate | 2018 |
| White Rabbit Publicity Ltd | Professional & scientific | 2009 |
| Wicks (Properties) Limited | Real estate | 2014 |
| Wide Adventures Services Ltd | Professional & scientific | 2019 |
| Wild Things Gifts Ltd | Wholesale & retail | 2009 |
| Wilde Stuff Ltd | Other services | 2015 |
| Wilkinson-Brice Health Advisory Ltd | Professional & scientific | 2026 |
| William Chambers Limited | Health & social care | 2013 |
| William Vaughan Holdings Limited | Financial services | 1931 |
| Winkworth Associates Limited | Professional & scientific | 2009 |
| Wits Foundation UK | Professional & scientific | 2001 |
| Woodbury Service Station Limited | | 1993 |
| Woodlee Freehold Limited | Real estate | 2021 |
| Woodleigh Coach House Limited | Hospitality | 2017 |
| Woosworld Ltd | Wholesale & retail | 2022 |
| World Fireworks Championship Limited | Arts & recreation | 2003 |
| World of Catkins Ltd | Wholesale & retail | 2022 |
| World of Stone Limited | Extraterritorial | 2005 |
| World Warrior Limited | Information & communication | 2014 |
| WSM ST Marys Garage Car Sales Ltd | Wholesale & retail | 2021 |
| Xswraps Ltd | Manufacturing | 2018 |
| Yellow Mouse Studios Limited | Arts & recreation | 2015 |
| Your Sorted Nest Limited | Administrative & support | 2023 |
| YP SEE Ltd | Education | 2023 |
| Zeal Monk Limited | Real estate | 2023 |
| ZEN Games Ltd | Manufacturing | 2023 |
| Zenen Ltd | Professional & scientific | 2012 |
| Zintec (Agri) Limited | Agriculture & fishing | 2013 |
| ZMB Property Limited | Real estate | 2019 |
| Zorbell Limited | Financial services | 2013 |